In which of the following equilibrium reactions,the equilibrium would shift to the right,if total pressure is increased?

  • A
    $N_2(g) + 3H_2(g) \rightleftharpoons 2NH_3(g)$
  • B
    $H_2(g) + I_2(g) \rightleftharpoons 2HI(g)$
  • C
    $H_2(g) + Cl_2(g) \rightleftharpoons 2HCl(g)$
  • D
    $N_2O_4(g) \rightleftharpoons 2NO_2(g)$

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On the basis of the $Le \ Chatelier$ principle,explain how temperature and pressure can be adjusted to increase the yield of ammonia in the following reaction: $N_{2(g)} + 3H_{2(g)} \rightleftharpoons 2NH_{3(g)}$; $\Delta H = -92.38 \ kJ \ mol^{-1}$. What will be the effect of the addition of argon to the above reaction mixture at constant volume?

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