In which of the following reactions does the heat change represent the heat of formation of water?

The heat of neutralisation of $NH_4OH$ and $HCl$ is:

Given that the bond energy of hydrogen-hydrogen bond is $436 \ kJ/mol$,that of hydrogen-oxygen bond is $464 \ kJ/mol$,and those in oxygen molecules $496 \ kJ/mol$,what is the approximate heat of reaction for $2H_2 + O_2 \longrightarrow 2H_2O$ ? .....$kJ/mol$

The standard heat of formation $\left(\Delta_{f} H_{298}^{0}\right)$ of ethane in $kJ/mol$,if the heat of combustion of ethane,hydrogen and graphite are $-1560$,$-286$,and $-393.5 \; kJ/mol,$ respectively is ........... $kJ/mol$.

Given below are two statements: One is labelled as Assertion $(A)$ and the other is labelled as Reason $(R)$
Assertion $(A)$: Enthalpy of neutralisation of strong monobasic acid with strong monoacidic base is always $-57 \ kJ \ mol^{-1}$.
Reason $(R)$: Enthalpy of neutralisation is the amount of heat liberated when one mole of $H^{+}$ ions furnished by acid combine with one mole of $OH^{-}$ ions furnished by base to form one mole of water.
In the light of the above statements,choose the correct answer from the options given below.

If the standard molar enthalpy change for combustion of graphite powder is $-2.48 \times 10^{2} \ kJ \ mol^{-1}$,the amount of heat generated on combustion of $1 \ g$ of graphite powder is $..... \ kJ$.
(Nearest integer)