In which solution,solute is liquid and solvent is gas?

The osmotic pressure of $0.1 \ M$ monobasic acid of $pH \ 3$ at $27^{\circ} C$ is (in $atm$)

At $80\,^oC$,the vapour pressure of pure liquid $A$ is $520\, mm\,Hg$ and that of pure liquid $B$ is $1000\, mm\,Hg$. If a mixture of $A$ and $B$ boils at $80\,^oC$ and $1\, atm$ pressure,the amount of $A$ in the mixture is ........... $mol\,\%$.

$1.22 \, g$ of an organic acid is separately dissolved in $100 \, g$ of benzene $(K_{b}=2.6 \, K \, kg \, mol^{-1})$ and $100 \, g$ of acetone $(K_{b}=1.7 \, K \, kg \, mol^{-1})$. The acid is known to dimerize in benzene but remain as a monomer in acetone. The boiling point of the solution in acetone increases by $0.17^{\circ} C$.
The increase in boiling point of solution in benzene in $^{\circ} C$ is $x \times 10^{-2}$. The value of $x$ is ..... .(Nearest integer)
$[$ Atomic mass : $C=12.0, H=1.0, O=16.0]$

What is boiling point? What is freezing point?

Which of the following pairs of solutions is isotonic?
$A$. $18 \ g/L$ of glucose solution and $6 \ g/L$ of urea solution
$B$. $10 \ g/L$ of glucose solution and $10 \ g/L$ of urea solution
$C$. $0.01 \ M \ NaOH$ solution and $0.02 \ M$ glucose solution
$D$. $0.01 \ M \ NaCl$ solution and $0.01 \ M$ glucose solution
(Assume that $NaCl$ undergoes complete dissociation)