Iodine is released when potassium iodide reacts with

Which of the following is $NOT$ a redox reaction?

$A$ sample $(5.6 \ g)$ containing iron is completely dissolved in cold dilute $HCl$ to prepare $250 \ mL$ of solution. Titration of $25.0 \ mL$ of this solution requires $12.5 \ mL$ of $0.03 \ M \ KMnO_4$ solution to reach the end point. The number of moles of $Fe^{2+}$ present in the $250 \ mL$ solution is $x \times 10^{-2}$ (consider complete dissolution of $FeCl_2$). The amount of iron present in the sample is $y \%$ by weight. (Assume: $KMnO_4$ reacts only with $Fe^{2+}$ in the solution. Use: Molar mass of iron as $56 \ g \ mol^{-1}$)
$(1)$ The value of $x$ is. . . . .
$(2)$ The value of $y$ is. . . . .

In the reaction of sulphur with concentrated sulphuric acid,the oxidised product is $X$ and the reduced product is $Y$. $X$ and $Y$ are respectively:

Assign $A$,$B$,$C$,$D$ from the given type of reaction.
$BaCO_3 \downarrow + 2CH_3COOH \longrightarrow Ba(CH_3COO)_2 + CO_2 \uparrow + H_2O$

Which of the following will not change the orange colour of $K_2Cr_2O_7$ into green colour in an acidic medium?