Knowing the electron gain enthalpy values for $O \rightarrow O^{-}$ and $O \rightarrow O^{2-}$ as $-141 \ kJ \ mol^{-1}$ and $702 \ kJ \ mol^{-1}$ respectively,how can you account for the formation of a large number of oxides having $O^{2-}$ species and not $O^{-}$?
(Hint: Consider lattice energy factor in the formation of compounds).

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The stability of an ionic compound is primarily determined by its lattice energy. $A$ higher lattice energy leads to greater stability of the compound.
Lattice energy is directly proportional to the product of the charges on the ions. When a metal reacts with oxygen,the lattice energy of an oxide containing $O^{2-}$ ions is significantly higher than that of an oxide containing $O^{-}$ ions.
Although the second electron gain enthalpy for oxygen is endothermic $(702 \ kJ \ mol^{-1})$,this energy is more than compensated for by the large amount of lattice energy released during the formation of the crystal lattice with $O^{2-}$ ions. Therefore,oxides containing $O^{2-}$ are more stable than those containing $O^{-}$.

Explore More

Similar Questions

In which of the following processes is energy released?

Difficult
View Solution

The second electron affinity of an element is ...

The correct order of electron affinity is

The formation of the oxide ion $O^{2-}_{(g)}$ requires first an exothermic and then an endothermic step as shown below:
$O_{(g)} + e^{-} \to O^{-}_{(g)}; \Delta H = -142 \, kJ \, mol^{-1}$
$O^{-}_{(g)} + e^{-} \to O^{2-}_{(g)}; \Delta H = 844 \, kJ \, mol^{-1}$
This is because:

Which one of the elements has the maximum electron affinity?

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo