Match the following reactants with their corresponding products:
Reactants:
$(A)$ $C_2H_5Cl$,moist $Ag_2O$
$(B)$ $C_2H_5Cl$,ethanolic $AgCN$
$(C)$ $C_2H_5Cl$,ethanolic $AgNO_2$
$(D)$ $C_2H_5Cl$,ethanolic $KOH$
Products:
$(i)$ $CH_3CH_2ONO$
$(ii)$ $C_2H_4$
$(iii)$ $CH_3CH_2OH$
$(iv)$ $CH_3CH_2NC$
Select the correct match:

  • A
    $A-iii, B-iv, C-i, D-ii$
  • B
    $A-i, B-ii, C-iii, D-iv$
  • C
    $A-iii, B-i, C-iv, D-ii$
  • D
    $A-iv, B-i, C-ii, D-iii$

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Explain the factors affecting $S_{N}1$ reaction.

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$(a) \; (CH_3)_3CCH(OH)CH_3 \xrightarrow{conc. H_2SO_4} $
$(b) \; (CH_3)_2CHCH(Br)CH_3 \xrightarrow{alc. KOH} $
$(c) \; (CH_3)_2CHCH(Br)CH_3 \xrightarrow{(CH_3)_3CO^{-}K^{+}} $
$(d) \; (CH_3)_2C(OH)CH_2CHO \xrightarrow{\Delta} $
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The major product of the above reaction is:

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Explain the mechanism of the bimolecular nucleophilic substitution $(S_N2)$ reaction with the example of $CH_3Cl$.

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