Match the following:

List-$I$	List-$II$
$A$. Amide	$I$. Carbylamine reaction
$B$. Nitrile	$II$. Hinsberg's reagent
$C$. $C_6H_5SO_2Cl$	$III$. Hofmann's bromamide reaction
$D$. $1^{\circ}$-Amine	$IV$. $LiAlH_4$

Which one of the following methods is neither meant for the synthesis nor for separation of amines?

Consider the following reaction sequence:
$p$-Nitrotoluene $\xrightarrow{P} Q$ $\xrightarrow{R} S$ $\xrightarrow{H_2O} T$
$S \xrightarrow{U} \text{Benzoic acid}$
Identify the correct statements from the following:
$(A) P = H_2/Pd, \text{ethanol}; R = NaNO_2/HCl; U = 1. H_3PO_2, 2. KMnO_4-KOH, \text{heat}$
$(B) P = Sn/HCl; R = HNO_2; S = p-\text{toluenediazonium chloride}$
$(C) S = p-\text{toluenediazonium chloride}; T = p-\text{cresol}; U = 1. CH_3CH_2OH, 2. KMnO_4-KOH, \text{heat}$
$(D) Q = p-\text{nitrobenzoic acid}; R = H_2/Pd, \text{ethanol}; T = p-\text{cresol}$
Which of the following combinations is correct?

Number of structural isomers of $C_4H_{11}N$.

Product $D$ is:-

The major product of the following reaction is: