Maximum deviation from ideal gas behavior is expected from which of the following gases?

At low pressures,van der Waals' equation is written as $(P + \frac{a}{V^2})V = RT$. The compressibility factor $Z$ will be

What is the unit of the Van der Waals constant $a$?

At low pressure,Vander Waals equation is written as $(P + \frac{a}{V^2})V = RT$. The compressibility factor is then equal to

Gases deviate from the ideal gas behaviour because their molecules

At a given temperature $T$,gases $Ne$,$Ar$,$Xe$,and $Kr$ are found to deviate from ideal gas behaviour. Their equation of state is given as $P = \frac{RT}{V - b}$ at $T$. Here,$b$ is the van der Waals constant. Which gas will exhibit a steeper increase in the plot of $Z$ (compression factor) versus $P$?