Name the following halides according to the $IUPAC$ system and classify them as alkyl,allyl,benzyl (primary,secondary,tertiary),vinyl,or aryl halides:
$(i)$ $[CH_3]_2CHCH(Cl)CH_3$
$(ii)$ $CH_3CH_2CH(CH_3)CH(C_2H_5)Cl$
$(iii)$ $CH_3CH_2C[CH_3]_2CH_2I$
$(iv)$ $[CH_3]_3CCH_2CH(Br)C_6H_5$
$(v)$ $CH_3CH(CH_3)CH(Br)CH_3$
$(vi)$ $CH_3C(C_2H_5)_2CH_2Br$
$(vii)$ $CH_3C(Cl)(C_2H_5)CH_2CH_3$
$(viii)$ $CH_3CH=C(Cl)CH_2CH(CH_3)_2$
$(ix)$ $CH_3CH=CHC(Br)(CH_3)_2$
$(x)$ $p-ClC_6H_4CH_2CH(CH_3)_2$
$(xi)$ $m-ClCH_2C_6H_4CH_2C(CH_3)_3$
$(xii)$ $o-BrC_6H_4CH(CH_3)CH_2CH_3$
$(i)$ $[CH_3]_2CHCH(Cl)CH_3$
$(ii)$ $CH_3CH_2CH(CH_3)CH(C_2H_5)Cl$
$(iii)$ $CH_3CH_2C[CH_3]_2CH_2I$
$(iv)$ $[CH_3]_3CCH_2CH(Br)C_6H_5$
$(v)$ $CH_3CH(CH_3)CH(Br)CH_3$
$(vi)$ $CH_3C(C_2H_5)_2CH_2Br$
$(vii)$ $CH_3C(Cl)(C_2H_5)CH_2CH_3$
$(viii)$ $CH_3CH=C(Cl)CH_2CH(CH_3)_2$
$(ix)$ $CH_3CH=CHC(Br)(CH_3)_2$
$(x)$ $p-ClC_6H_4CH_2CH(CH_3)_2$
$(xi)$ $m-ClCH_2C_6H_4CH_2C(CH_3)_3$
$(xii)$ $o-BrC_6H_4CH(CH_3)CH_2CH_3$
(A) $(i)$ $2-Chloro-3-methylbutane$ (Secondary alkyl halide)
$(ii)$ $3-Chloro-4-methylhexane$ (Secondary alkyl halide)
$(iii)$ $1-Iodo-2,2-dimethylbutane$ (Primary alkyl halide)
$(iv)$ $1-Bromo-3,3-dimethyl-1-phenylbutane$ (Secondary benzyl halide)
$(v)$ $2-Bromo-3-methylbutane$ (Secondary alkyl halide)
$(vi)$ $1-Bromo-2-ethyl-2-methylbutane$ (Primary alkyl halide)
$(vii)$ $3-Chloro-3-methylpentane$ (Tertiary alkyl halide)
$(viii)$ $3-Chloro-5-methylhex-2-ene$ (Vinyl halide)
$(ix)$ $4-Bromo-4-methylpent-2-ene$ (Allyl halide)
$(x)$ $1-Chloro-4-(2-methylpropyl)benzene$ (Aryl halide)
$(xi)$ $1-(Chloromethyl)-3-(2,2-dimethylpropyl)benzene$ (Primary benzyl halide)
$(xii)$ $1-Bromo-2-(1-methylpropyl)benzene$ (Aryl halide)
$(ii)$ $3-Chloro-4-methylhexane$ (Secondary alkyl halide)
$(iii)$ $1-Iodo-2,2-dimethylbutane$ (Primary alkyl halide)
$(iv)$ $1-Bromo-3,3-dimethyl-1-phenylbutane$ (Secondary benzyl halide)
$(v)$ $2-Bromo-3-methylbutane$ (Secondary alkyl halide)
$(vi)$ $1-Bromo-2-ethyl-2-methylbutane$ (Primary alkyl halide)
$(vii)$ $3-Chloro-3-methylpentane$ (Tertiary alkyl halide)
$(viii)$ $3-Chloro-5-methylhex-2-ene$ (Vinyl halide)
$(ix)$ $4-Bromo-4-methylpent-2-ene$ (Allyl halide)
$(x)$ $1-Chloro-4-(2-methylpropyl)benzene$ (Aryl halide)
$(xi)$ $1-(Chloromethyl)-3-(2,2-dimethylpropyl)benzene$ (Primary benzyl halide)
$(xii)$ $1-Bromo-2-(1-methylpropyl)benzene$ (Aryl halide)
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Similar Questions
Match the structure in Column-$I$ with its common name in Column-$II$ and $IUPAC$ name in Column-$III$.
Column-$I$ (Structure)
Column-$II$ (Common Name) and Column-$III$ ($IUPAC$ Name)
$(A)$ $CH_3CH_2CH_2Cl$
$(iv)$ $n$-Propyl chloride,$(q)$ $1$-Chloropropane
$(B)$ $CH_3CHClCH_3$
$(ii)$ Isopropyl chloride,$(p)$ $2$-Chloropropane
$(C)$ $CH_3CH(CH_3)CH_2Cl$
$(iii)$ Isobutyl chloride,$(s)$ $1$-Chloro-$2$-methylpropane
$(D)$ $(CH_3)_3CCH_2Cl$
$(i)$ Neopentyl chloride,$(r)$ $1$-Chloro-$2,2$-dimethylpropane
| Column-$I$ (Structure) | Column-$II$ (Common Name) and Column-$III$ ($IUPAC$ Name) |
| $(A)$ $CH_3CH_2CH_2Cl$ | $(iv)$ $n$-Propyl chloride,$(q)$ $1$-Chloropropane |
| $(B)$ $CH_3CHClCH_3$ | $(ii)$ Isopropyl chloride,$(p)$ $2$-Chloropropane |
| $(C)$ $CH_3CH(CH_3)CH_2Cl$ | $(iii)$ Isobutyl chloride,$(s)$ $1$-Chloro-$2$-methylpropane |
| $(D)$ $(CH_3)_3CCH_2Cl$ | $(i)$ Neopentyl chloride,$(r)$ $1$-Chloro-$2,2$-dimethylpropane |
Difficult
View SolutionWrite structures of the following compounds:
$(i)$ $2-$Chloro$-3-$methylpentane
$(ii)$ $1-$Chloro$-4-$ethylcyclohexane
$(iii)$ $4-$tert-Butyl$-3-$iodoheptane
$(iv)$ $1,4-$Dibromobut$-2-$ene
$(v)$ $1-$Bromo$-4-$sec-butyl$-2-$methylbenzene.
$(i)$ $2-$Chloro$-3-$methylpentane
$(ii)$ $1-$Chloro$-4-$ethylcyclohexane
$(iii)$ $4-$tert-Butyl$-3-$iodoheptane
$(iv)$ $1,4-$Dibromobut$-2-$ene
$(v)$ $1-$Bromo$-4-$sec-butyl$-2-$methylbenzene.
Easy
View SolutionWhich among the following is $NOT$ an allylic halide?
Given below are two statements,one is labeled as Assertion $(A)$ and the other is labeled as Reason $(R)$.
Assertion $(A)$: $CH_2=CH-CH_2-Cl$ is an example of an allyl halide.
Reason $(R)$: Allyl halides are the compounds in which the halogen atom is attached to an $sp^3$ hybridized carbon atom,which is adjacent to a carbon-carbon double bond.
In the light of the two above statements,choose the most appropriate answer from the options given below:
Assertion $(A)$: $CH_2=CH-CH_2-Cl$ is an example of an allyl halide.
Reason $(R)$: Allyl halides are the compounds in which the halogen atom is attached to an $sp^3$ hybridized carbon atom,which is adjacent to a carbon-carbon double bond.
In the light of the two above statements,choose the most appropriate answer from the options given below:
DifficultJEE MAIN 2024
View SolutionWhich of the following are vinyl chlorides?
$(a)$ $3\text{-chlorocyclohexene}$
$(b)$ $1\text{-chlorocyclohexene}$
$(c)$ $4\text{-chlorobut-1-ene}$
$(d)$ $1\text{-chloroethene}$
$(e)$ $3\text{-chlorobut-1-yne}$
$(f)$ $3\text{-chloro-2-methylpropene}$
$(a)$ $3\text{-chlorocyclohexene}$
$(b)$ $1\text{-chlorocyclohexene}$
$(c)$ $4\text{-chlorobut-1-ene}$
$(d)$ $1\text{-chloroethene}$
$(e)$ $3\text{-chlorobut-1-yne}$
$(f)$ $3\text{-chloro-2-methylpropene}$
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