Nitrochloroform (Chloropicrin) is prepared by the action of chloroform and:

  • A
    Hot aqueous solution of $KNO_3$
  • B
    Hot aqueous solution of $NaNO_2$
  • C
    Hot concentrated nitric acid
  • D
    Hot dilute $HCl$ $+$ aq. $NaNO_2$ solution

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Compound $A$ with molecular formula $C_4H_9Br$ is treated with aqueous $KOH$ solution. The rate of this reaction depends upon the concentration of compound $A$ only. When another optically active isomer $B$ of this compound was treated with aqueous $KOH$ solution,the rate of reaction was found to be dependent on the concentration of both the compound and $KOH$.
$(i)$ Write down the structural formula of both compounds $A$ and $B$.
$(ii)$ Out of these two compounds,which one will be converted to the product with inverted configuration?

The following reaction,$(CH_3)_3CBr + H_2O \rightarrow (CH_3)_3COH + HBr$,is an example of:

The following bimolecular elimination reaction $(E_2)$ is carried out with different halogen leaving groups. The per cent yield of the two products ($2$-hexene and $1$-hexene) for each leaving group is listed below.
Leaving groupConj. Acid $pK_a$$\%$-yield of $2$-hexene$\%$-yield of $1$-hexene
$X = I$$-10$$81\%$$19\%$
$X = Br$$-9$$72\%$$28\%$
$X = Cl$$-7$$67\%$$33\%$
$X = F$$3.2$$30\%$$70\%$

Which of the following statement$(s)$ is/are true concerning this series of $E_2$ reactions?

Arrange each set of compounds in order of increasing boiling points.
$(i)$ Bromomethane,Bromoform,Chloromethane,Dibromomethane.
$(ii)$ $1-$Chloropropane,Isopropyl chloride,$1-$Chlorobutane.

Identify the product of the following reaction:
(See image for reaction scheme)
Product; The product is:

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