Of all the three common mineral acids,only sulphuric acid is found to be suitable for making the solution acidic in redox titrations involving $KMnO_4$ because:

Why is it necessary to wash the precipitate before measuring it quantitatively?

Estimation of $CO$ is done by using:

Below are two statements. One is labeled as Assertion $(A)$ and the other as Reason $(R).$
Assertion $(A):$ When using an aqueous solution of $KOH$ in a volumetric analysis,its concentration should be checked before use.
Reason $(R):$ $KOH$ solution absorbs atmospheric $CO_2$ when it gets old.
In the context of the above statements,choose the correct answer from the options given below:

The ammonia evolved from the treatment of $0.30 \, g$ of an organic compound for the estimation of nitrogen was passed in $100 \, mL$ of $0.1 \, M$ sulphuric acid. The excess of acid required $20 \, mL$ of $0.5 \, M$ sodium hydroxide solution for complete neutralization. The organic compound is:

Given below are two statements
Statement $I$: Aqueous solution of $K_2Cr_2O_7$ is preferred as a primary standard in volumetric analysis over $Na_2Cr_2O_7$ aqueous solution.
Statement $II$: $K_2Cr_2O_7$ has a higher solubility in water than $Na_2Cr_2O_7$.
In the light of the above statements,choose the correct answer from the options given below: