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Explain the purification of Zirconium and Titanium metals.

Hoop's process is used for the purification of the metal:

Name the common elements present in the anode mud in electrolytic refining of copper. Why are they so present?

Match Column $-I$ with Column $-II$ and select the correct answer using the codes given below.
Column $-I$ Column $-II$
$(i)$ Iron and copper $(P)$ Poling
$(ii)$ Zirconium and Titanium $(Q)$ Bessemerisation
$(iii)$ Lead and Tin $(R)$ Van Arkel
$(iv)$ Copper and Tin $(S)$ Liquation

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In the electrolytic refining of copper,$Ag$ and $Au$ are found

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