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| Column - $I$ and $II$ | Column - $III$ |
|---|---|
| $(A).$ Rosenmund reaction - $(i).$ $H_2, Pd, BaSO_4$ | $(p).$ Benzene to benzaldehyde |
| $(B).$ Stephen reaction - $(iii).$ $SnCl_2, HCl$ | $(q).$ Benzoyl chloride to benzaldehyde |
| $(C).$ Etard reaction - $(iv).$ $CrO_2Cl_2, CS_2$ | $(r).$ Toluene to chromium complex |
| $(D).$ Gatterman-Koch reaction - $(ii).$ $CO, HCl$ anhydrous $AlCl_3/CuCl$ | $(s).$ $RCN \to RCHO$ |
| Column $-I$ (Reactant) | Column $-II$ (Reaction Condition) | Column $-III$ (Product) |
|---|---|---|
| $A$. $CH_3CN + C_6H_5MgBr$ | $i$. $Ether, H_3O^+$ | $p$. Benzaldehyde |
| $B$. $Benzene + CH_3COCl$ | $ii$. $Hg^{2+}, H_2SO_4, H_2O$ | $q$. Acetophenone |
| $C$. $Toluene$ | $iii$. $Anhydrous AlCl_3$ | $r$. Propiophenone |
| $D$. $Phenyl ethyne$ | $iv$. $x. Cl_2, hv$; $y. H_2O, 373 \ K$ | $s$. Acetaldehyde |
| Item-$I$ | Item-$II$ |
| $I$. Benzene | $P$. $HCl$ and $SnCl_2, H_3O^{+}$ |
| $II$. Benzonitrile | $Q$. $H_2, Pd-BaSO_4, S$ and quinoline |
| $III$. Benzoyl Chloride | $R$. $CO, HCl$ and $AlCl_3$ |
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