Predict the major product $G$ of the following reaction sequence starting from $p$-nitrotoluene.

  • A
    $2-$chloro$-4-$bromotoluene
  • B
    $3-$chloro$-4-$bromotoluene
  • C
    $2-$chloro$-5-$bromotoluene
  • D
    $3-$chloro$-5-$bromotoluene

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You have been given four bottles marked $A, B, C$ and $D$ each containing one of the organic compounds given below:
$I: C_6H_5CH_2NH_2$$II: C_6H_5CH_2COOH$
$III: C_6H_5CH_2CH_3$$IV: C_6H_5CH_2CH(NH_2)COOH$

The following observations were made:
$(i)$ The compound in bottle $A$ did not dissolve in either $1 \ N \ NaOH$ or $1 \ N \ HCl$.
$(ii)$ The compound in bottle $B$ dissolved in $1 \ N \ NaOH$ but not in $1 \ N \ HCl$.
$(iii)$ The compound in bottle $C$ dissolved in both $1 \ N \ NaOH$ and $1 \ N \ HCl$.
$(iv)$ The compound in bottle $D$ did not dissolve in $1 \ N \ NaOH$ but dissolved in $1 \ N \ HCl$.
$(a)$ Indicate the compounds in: bottle $A = \dots$,bottle $B = \dots$,bottle $C = \dots$ and bottle $D = \dots$.
$(b)$ The compound with the highest solubility in distilled water is .......

Identify the product $B$ in the following reaction:
$C_6H_5NH_2$ $\xrightarrow[0^\circ-5^\circ C]{NaNO_2/HCl} A$ $\xrightarrow{Ph-N(CH_3)_2} B$

Difficult
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Write the chemical reactions for the following conversions:
$1.$ Aniline to Picric acid
$2.$ Ethanal to Butan$-2-$ol

An organic compound $A$ reacts with $NH_3$ on heating to give $B$. Compound $B$ reacts with $Br_2$ in the presence of $KOH$ to give $CH_3CH_2NH_2$. What is $A$?

Match List-$I$ with List-$II$:
List-$I$ List-$II$
$A$. Benzenesulphonyl chloride $I$. Test for primary amines
$B$. Hoffmann bromamide reaction $II$. Anti Saytzeff
$C$. Carbylamine reaction $III$. Hinsberg reagent
$D$. Hoffmann orientation $IV$. Known reaction of isocyanates

Choose the correct answer from the options given below.

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