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Match Column-$I$ with Column-$II$ :
| Column-$I$ | Column-$II$ |
| :--- | :--- |
| $(A)$ Cyclopentanone + $2,4-$$DNP$ $\xrightarrow{\text{mild } H^+}$ Cyclopentanone$-2,4-$$DNP$ derivative | $(P)$ Electrophilic substitution |
| $(B)$ $4-$phenyl$-2-$methylbutan$-2-$ol $\xrightarrow{\text{Conc. } H_2SO_4}$ $1,1-$dimethyl$-1,2,3,4-$tetrahydronaphthalene | $(Q)$ Nucleophilic substitution |
| $(C)$ $4-$chlorocyclohexanethiol $\xrightarrow{\text{Base}}$ $7-$thiabicyclo[$2.2$.$1$]heptane | $(R)$ Nucleophilic addition |

Which of the following reactions produce ethyl cyanide $(CH_3 CH_2 CN)$ as a major product?
$1.$ $CH_3 CH_2 CH=NOH \xrightarrow{(CH_3 CO)_2 O} CH_3 CH_2 CN$
$2.$ $CH_3 CH_2 Cl \xrightarrow{\text{Ethanolic } KCN} CH_3 CH_2 CN$
$3.$ $CH_3 CH_2 Cl \xrightarrow{\text{Ethanolic } AgCN} CH_3 CH_2 NC$
$4.$ $CH_3 CH_2 CON(CH_3)_2 \xrightarrow[\text{Pyridine, } 70^{\circ} C]{C_6 H_5 SO_2 Cl} CH_3 CH_2 CN$

Match List-$I$ with List-$II$.
List-$I$ (Name of reaction) List-$II$ (Reagent used)
$A$. Hell-Volhard-Zelinsky reaction $I$. $NaOH + I_2$
$B$. Iodoform reaction $II$. $(i) CrO_2Cl_2, CS_2; (ii) H_2O$
$C$. Etard reaction $III$. $(i) Br_2 / \text{red phosphorus}; (ii) H_2O$
$D$. Gatterman-Koch reaction $IV$. $CO, HCl, \text{anhyd. } AlCl_3$

Choose the correct answer from the options given below:

Choose the response that matches the correct functional group classification with the following group of structural formulas.

Match the reactions given in Column-$I$ with the appropriate reagents in Column-$II$.
| Column-$I$ (Reaction) | Column-$II$ (Reagent) |
| :--- | :--- |
| $(A)$ $2CH_3COOH \rightarrow (CH_3CO)_2O$ | $(i)$ $(I) NH_3, (II) \Delta, -H_2O$ |
| $(B)$ Phthalic acid $\rightarrow$ Phthalamide | $(ii)$ $(I) Br_2 / \text{red phosphorous}, (II) H_2O$ |
| $(C)$ $CH_3CH_2COOH \rightarrow CH_3CHBrCOOH$ | $(iii)$ $Br_2 / FeBr_3$ |
| $(D)$ Benzoic acid $\rightarrow$ $m$-Bromobenzoic acid | $(iv)$ $H^+, \Delta \text{ OR } P_2O_5, \Delta$ |

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