Some statements are given below $-$
$(a)$ Coordination compounds $[Pt(NH_3)_3(NCS)]$ and $[Pt(NH_3)_3(SCN)]$ are examples of linkage isomerism.
$(b)$ In the coordination compound $K_4[Ni(CN)_4]$, the oxidation state of nickel is zero.
$(c)$ The hybridization, shape and magnetic moment of $K_3[Cu(CN)_4]$ are respectively $dsp^2$, square planar, $1.73 \ B.M.$
$(d)$ $[Cr(NCS)(NH_3)_5][ZnCl_4]$ exhibits only linkage isomerism.
$(a)$ Coordination compounds $[Pt(NH_3)_3(NCS)]$ and $[Pt(NH_3)_3(SCN)]$ are examples of linkage isomerism.
$(b)$ In the coordination compound $K_4[Ni(CN)_4]$, the oxidation state of nickel is zero.
$(c)$ The hybridization, shape and magnetic moment of $K_3[Cu(CN)_4]$ are respectively $dsp^2$, square planar, $1.73 \ B.M.$
$(d)$ $[Cr(NCS)(NH_3)_5][ZnCl_4]$ exhibits only linkage isomerism.
- Aonly $a, b, c$ are correct
- Bonly $a, b$ are correct
- Conly $b, c, d$ are correct
- DAll are correct
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Similar Questions
Match each coordination compound in List-$I$ with an appropriate pair of characteristics from List-$II$ and select the correct answer using the code given below the lists. $\{en = H_2NCH_2CH_2NH_2\}$,atomic numbers:$\{Ti = 22; Cr = 24; Co = 27; Pt = 78\}$
List-$I$
List-$II$
$P$. $[Cr(NH_3)_4Cl_2]Cl$
$1$. Paramagnetic and exhibits ionisation isomerism
$Q$. $[Ti(H_2O)_5Cl](NO_3)_2$
$2$. Diamagnetic and exhibits cis-trans isomerism
$R$. $[Pt(en)(NH_3)Cl]NO_3$
$3$. Paramagnetic and exhibits cis-trans isomerism
$S$. $[Co(NH_3)_4(NO_3)_2]NO_3$
$4$. Diamagnetic and exhibits ionisation isomerism
| List-$I$ | List-$II$ |
|---|---|
| $P$. $[Cr(NH_3)_4Cl_2]Cl$ | $1$. Paramagnetic and exhibits ionisation isomerism |
| $Q$. $[Ti(H_2O)_5Cl](NO_3)_2$ | $2$. Diamagnetic and exhibits cis-trans isomerism |
| $R$. $[Pt(en)(NH_3)Cl]NO_3$ | $3$. Paramagnetic and exhibits cis-trans isomerism |
| $S$. $[Co(NH_3)_4(NO_3)_2]NO_3$ | $4$. Diamagnetic and exhibits ionisation isomerism |
Difficult
View Solution$1\,L, 0.02\,M$ solution of $[Co(NH_3)_5SO_4]Br$ is mixed with $1\,L, 0.02\,M$ solution of $[Co(NH_3)_5Br]SO_4$. The resulting solution is divided into two equal parts $(X)$ and treated with excess $AgNO_3$ solution and $BaCl_2$ solution respectively as shown below:
$1\,L$ Solution $(X) + AgNO_3$ solution (excess) $\rightarrow Y$
$1\,L$ Solution $(X) + BaCl_2$ solution (excess) $\rightarrow Z$
The number of moles of $Y$ and $Z$ respectively are:
$1\,L$ Solution $(X) + AgNO_3$ solution (excess) $\rightarrow Y$
$1\,L$ Solution $(X) + BaCl_2$ solution (excess) $\rightarrow Z$
The number of moles of $Y$ and $Z$ respectively are:
The given complex $M(ABCDEF)$ exhibits which of the following isomerism?
Medium
View SolutionWhich of the following change the colour of the aqueous solution of $FeCl_3$?
Difficult
View SolutionGiven below are two statements:
Statement $I$ : Dimethyl glyoxime forms a six-membered covalent chelate when treated with $NiCl_2$ solution in presence of $NH_4OH$.
Statement $II$ : Prussian blue precipitate contains iron both in $(+2)$ and $(+3)$ oxidation states.
In the light of the above statements,choose the most appropriate answer from the options given below:
Statement $I$ : Dimethyl glyoxime forms a six-membered covalent chelate when treated with $NiCl_2$ solution in presence of $NH_4OH$.
Statement $II$ : Prussian blue precipitate contains iron both in $(+2)$ and $(+3)$ oxidation states.
In the light of the above statements,choose the most appropriate answer from the options given below:
DifficultJEE MAIN 2024
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