State the contribution of Nyholm and Gillespie in $VSEPR$ theory.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Nyholm and Gillespie $(1957)$ refined the $VSEPR$ model by explaining the important difference between the lone pair and bonding pairs of electrons.
While the lone pairs are localised on the central atom,each bonded pair is shared between two atoms.
As a result,the lone pair electrons in a molecule occupy more space compared to the bonding pairs of electrons.
This results in greater repulsion between lone pairs of electrons compared to the lone pair-bond pair and bond pair-bond pair repulsions.
These repulsion effects result in deviations from idealised shapes and alterations in bond angles in molecules.

Explore More

Similar Questions

The shape of the $BF_3$ molecule is:

Are all the five bonds in $PCl_{5}$ molecule equivalent? Justify your answer.

Which of the following substances has the minimum bond angle?

Which of the following species are isostructural: $NO^{-}_3, CO^{2-}_3, ClO^{-}_3,$ and $SO_3$?

Difficult
View Solution

The number of molecules/ions having a trigonal bipyramidal shape is $........$.
$PF_5, BrF_5, PCl_5, [PtCl_4]^{2-}, BF_3, Fe(CO)_5$

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo