State True or False for the following statements:
$(i)$ Positive and negative ions are formed by homolytic cleavage of a covalent bond.
$(ii)$ Positive and negative ions are formed by heterolytic cleavage of a covalent bond.
$(iii)$ Only homolytic cleavage is possible in the $C-Cl$ bond of $CH_3-Cl$.
$(iv)$ If heterolytic cleavage of a bond occurs,then ionic or polar type reactions take place.

Based on the provided energy profile diagram,transition state $2$ $(T.S. 2)$ is structurally most likely similar to which of the following?

The major product $(C)$ is

For the given molecule, $x$, the preferred site for the attack of the electrophile is:

The major product in the given reaction is :

Match the reactions in column $I$ with appropriate types of steps/reactive intermediate involved in these reactions as given in column $II$.
| Column $I$ | Column $II$ |
| :--- | :--- |
| $(A)$ $1-$phenylpentane$-1,4-$dione $\xrightarrow{aq. NaOH}$ $3-$phenylcyclopent$-2-$en$-1-$one | $(p)$ Nucleophilic substitution |
| $(B)$ $4-$chloro$-1-$phenylbutan$-1-$one $\xrightarrow{CH_3MgI}$ $2-$methyl$-2-$phenyltetrahydrofuran | $(q)$ Electrophilic substitution |
| $(C)$ $4-$hydroxy$-1-$phenylbutan$-1-$one $\xrightarrow{H_2SO_4}$ $2-$phenyl$-4,5-$dihydrofuran | $(r)$ Dehydration |
| $(D)$ $4-$methyl$-4-$phenylpentan$-1-$ol $\xrightarrow{H_2SO_4}$ $1,1-$dimethyl$-1,2,3,4-$tetrahydronaphthalene | $(s)$ Nucleophilic addition |
| | $(t)$ Carbanion |