Suppose the following reaction sequence: $CH \equiv CH$ $\xrightarrow[\text{excess}]{NaNH_2 / \text{liq. } NH_3} A$ $\xrightarrow{2 CH_3 - I} B$ $\xrightarrow{H_2 / Pd - BaSO_4, \text{ quinoline}} C$ and $C$ $\xrightarrow{H_2 / Pd - BaSO_4, \text{ quinoline}}$ $\xrightarrow{NaNH_2 / \text{liq. } NH_3} D$. How are $C$ and $D$ related?

  • A
    Geometrical isomer
  • B
    Diastereomers
  • C
    Enantiomer
  • D
    All of these

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An optically active alkene having molecular formula $C_8H_{16}$ gives acetone as one of the products on ozonolysis. The structure of the alkene is:

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$(iv)$ $1-Phenylbut-1-ene$

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Draw the $cis$ and $trans$ structures of $hex-2-ene$. Which isomer will have a higher $b.p.$ and why?

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