The $pK_{b}$ of dimethylamine and $pK_{a}$ of acetic acid are $3.27$ and $4.77$ respectively at $T(K)$. The correct option for the $pH$ of dimethylammonium acetate solution is :

  • A
    $8.50$
  • B
    $5.50$
  • C
    $7.75$
  • D
    $6.25$

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$A$ sample of $Na_2CO_3 \cdot H_2O$ weighing $0.62 \ g$ is added to $100 \ mL$ of $0.1 \ N \ (NH_4)_2SO_4$ solution. What will be the nature of the resulting solution?

At $25\, ^oC$,the dissociation constant of $CH_3COOH$ and $NH_4OH$ in aqueous solution are almost the same. The $pH$ of a $0.01\, N$ $CH_3COOH$ solution is $4.0$ at $25\, ^oC$. The $pH$ of a $0.01\, N$ $NH_4OH$ solution at the same temperature would be:

Arrange the following solutions in the decreasing order of $pOH$:
$A$. $0.01 \ M \ HCl$
$B$. $0.01 \ M \ NaOH$
$C$. $0.01 \ M \ CH_3COONa$
$D$. $0.01 \ M \ NaCl$

$1 \times 10^{-5} \ S \ M$ $AgNO_3$ is added to $1 \ L$ of a saturated solution of $AgBr$. The conductivity of this solution at $298 \ K$ is $......... \times 10^{-8} \ S \ m^{-1}$.
Given: $K_{sp}(AgBr) = 4.9 \times 10^{-13}$ at $298 \ K$,$\lambda^0_{Ag^{+}} = 6 \times 10^{-3} \ S \ m^2 \ mol^{-1}$,$\lambda^0_{Br^{-}} = 8 \times 10^{-3} \ S \ m^2 \ mol^{-1}$,$\lambda^0_{NO_3^-} = 7 \times 10^{-3} \ S \ m^2 \ mol^{-1}$.

Calculate the molar solubility of $AgCl$ at $25\,^oC$ in $3.0\ M\ NH_3$ ($K_{sp}$ of $AgCl = 2.0 \times 10^{-10}$,$K_f$ of $[Ag(NH_3)_2]^+ = 1.25 \times 10^7$) (in $M$)

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