The $pK_a$ of a weak acid $(HA)$ is $4.5$. The $pOH$ of an aqueous buffer solution of $HA$ in which $50\%$ of the acid is ionized is

The $pH$ of a buffer solution decreases by $0.02$ units when $0.12 \ g$ of acetic acid is added to $250 \ mL$ of a buffer solution of acetic acid and potassium acetate at $27^{\circ} C$. The buffer capacity of the solution is

$20 \, mL$ of $0.2 \, M \, HCN$ is mixed with $10 \, mL$ of $0.2 \, M \, NaOH$. Calculate the $pH$ of the resulting mixture. The $pKa$ value of $HCN$ is $5$.

The $pK_a$ of a weak acid is $4.8$. What should be the ratio of $\frac{[\text{acid}]}{[\text{salt}]}$, if a buffer of $pH = 5.8$ is required?

What is the value of $pOH$ if a buffer solution is prepared by mixing equal volumes of $0.4 \ M$ $NH_4OH$ and $0.5 \ M$ $NH_4Cl$ solutions? $(pK_b = 4.730)$

What would be the $pH$ of a solution obtained by mixing $5 \ g$ of acetic acid and $7.5 \ g$ of sodium acetate and making the volume equal to $500 \ mL$? $(K_a = 1.75 \times 10^{-5}, pK_a = 4.76)$