The activation energy for a simple chemical reaction $A \to B$ is ${E_a}$ in the forward direction. The activation energy for the reverse reaction:

  • A
    Is always double of ${E_a}$
  • B
    Is negative of ${E_a}$
  • C
    Is always less than ${E_a}$
  • D
    Can be less than or more than ${E_a}$

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Fill in the blanks:
$(a)$ $A$ catalyst ......... the change of equilibrium in reaction.
$(b)$ Boltzmann and Maxwell used ......... to explain the rate of reaction.

For the equilibrium $A_{(g)} \rightleftharpoons B_{(g)}$,$\Delta H$ is $-40 \ kJ/mol$. If the ratio of the activation energies of the forward $(E_f)$ and reverse $(E_b)$ reactions is $\frac{2}{3}$,then:

The value of the rate constant for the reaction $A + B \to \text{products}$ depends on:

Assertion : If the activation energy of a reaction is zero,temperature will have no effect on the rate constant.
Reason : Lower the activation energy,faster is the reaction.

Explain the collision theory of chemical reactions.

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