The amine which does not react with chlorofor | vedclass

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Question

(A) The reaction of primary amines with chloroform $(CHCl_3)$ and ethanolic potassium hydroxide $(KOH)$ to form isocyanides (carbylamines) is known as

Vedclass · Accepted Answer

$(CH_3)_2CH-NH-CH_3$

Vedclass · Answer

(A) The reaction of primary amines with chloroform $(CHCl_3)$ and ethanolic potassium hydroxide $(KOH)$ to form isocyanides (carbylamines) is known as the carbylamine reaction.This reaction is a characteristic test for primary amines.Secondary and tertiary amines do not undergo this reaction.In the given options:$A$ is a secondary amine $((CH_3)_2CH-NH-CH_3)$,$B$ is a primary amine $(C_6H_5-NH_2)$,$C$ is a primary amine $(3	ext{-bromo-4-methylaniline})$,$D$ is a primary amine $(4	ext{-bromoaniline})$.Therefore,the secondary amine $(CH_3)_2CH-NH-CH_3$ will not react.

The amine which does not react with chloroform and ethanolic potassium hydroxide is

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