The bond dissociation enthalpy of $H_{2(g)}$ and $N_{2(g)}$ are $436 \ kJ \ mol^{-1}$ and $940 \ kJ \ mol^{-1}$ respectively,and the enthalpy of formation of $NH_{3(g)}$ is $-45 \ kJ \ mol^{-1}$. The enthalpy of atomisation of $NH_{3(g)}$ is ..... $kJ \ mol^{-1}$.

  • A
    $ -1079 $
  • B
    $ -1169 $
  • C
    $ 1079 $
  • D
    $ 1169 $

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What will be the amount of heat evolved by burning $0.4 \ mol$ of methane? (Given heats of formation of $CH_4$,$CO_2$,and $H_2O$ are $-75$,$-400$,and $-240 \ kJ \ mol^{-1}$ respectively) ..... $kJ$

Calculate the $N-N$ bond energy in $N_2H_4$ from the given bond enthalpy data.
$\varepsilon_{N-H} = 393 \ kJ/mol$
$\varepsilon_{H-H} = 436 \ kJ/mol$
$\Delta H_{vap}[N_2H_{4(l)}] = 18 \ kJ/mol$
$N_2H_{4(l)} + H_{2(g)} \to 2NH_{3(g)} : \Delta H = -142 \ kJ/mol$
....... $kJ/mol$

Determine the enthalpy of formation for $H_2O_2(\ell)$,using the listed enthalpies of reaction:
$N_2H_{4(\ell)} + 2H_2O_{2(\ell)} \to N_{2(g)} + 4H_2O_{(\ell)}; \Delta _r H_1^o = -818 \, kJ/mol$
$N_2H_{4(\ell)} + O_{2(g)} \to N_{2(g)} + 2H_2O_{(\ell)}; \Delta _r H_2^o = -622 \, kJ/mol$
$H_{2(g)} + 1/2O_{2(g)} \to H_2O_{(\ell)}; \Delta _r H_3^o = -285 \, kJ/mol$
Calculate the value in $kJ/mol$.

If the standard enthalpies of formation of hydrazine and water are $+50.6 \, kJ/mol$ and $-285.9 \, kJ/mol$ respectively,calculate the $\Delta H$ for the following reaction: $N_2H_{4(g)} + O_{2(g)} \to N_{2(g)} + 2H_2O_{(l)}$ in $kJ \, mol^{-1}$.

Calculate the enthalpy of formation of nitric oxide $(NO)$ in $kJ \, mol^{-1}$ from the following data:
$NO_{(g)} + CO_{(g)} \rightarrow \frac{1}{2} N_{2(g)} + CO_{2(g)}; \Delta H^o = -372.2 \, kJ \, mol^{-1}$
$\Delta H_f^o (CO) = -110.5 \, kJ \, mol^{-1}$
$\Delta H_f^o (CO_2) = -393.5 \, kJ \, mol^{-1}$

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