The change in electrode potential of $Cr^{3+}/Cr_2O_7^{2-}$ electrode at $25 \ ^oC$ due to change in $pH$ of its electrolytic solution from $1$ to $3$ is ........... $V$ (Assume: $[Cr_2O_7^{2-}]$ and $[Cr^{3+}]$ remain constant). Use: $\frac{2.303RT}{F} = 0.06$.

  • A
    $0.21$
  • B
    $0.28$
  • C
    $0.14$
  • D
    No change

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Similar Questions

Calculate the cell potential at $298 \ K$ for the following cells:
$(a)$ $Cd \mid Cd^{2+}(0.02 \ M) \parallel H^{+}(1 \ M) \mid H_{2(g)}(1 \ bar) \mid Pt$ $\left[ E_{Cd^{2+} \mid Cd}^0 = -0.40 \ V \right]$
$(b)$ $Al \mid Al^{3+}(0.25 \ M) \parallel Zn^{2+}(0.15 \ M) \mid Zn_{(s)}$ $\left[ E_{Al^{3+} \mid Al}^0 = -1.66 \ V, E_{Zn^{2+} \mid Zn}^0 = -0.76 \ V \right]$

In the electrochemical cell $:$
$Zn \,|\,ZnSO_4\,(0.01\,M)\,||\,CuSO_4\,(1.0\,M)\,|\,Cu$
the $emf$ of this Daniell cell is $E_1.$ When the concentration of $ZnSO_4$ is changed to $1.0\,M$ and that of $CuSO_4$ changed to $0.01\,M,$ the $emf$ changes to $E_2.$ From the followings,which one is the relationship between $E_1$ and $E_2$ $?$ (Given,$RT/F = 0.059$)

What is the oxidation potential of $0.05 \, M \, H_2SO_4$ in volts?

The cell potential for $Zn | Zn^{2+}_{(aq)} || Sn^{x+}| Sn$ is $0.801 \ V$ at $298 \ K$. The reaction quotient for the above reaction is $10^{-2}$. The number of electrons involved in the given electrochemical cell reaction is .... (Given $E^{0}_{Zn^{2+}|Zn} = -0.763 \ V, E^{0}_{Sn^{x+}|Sn} = +0.008 \ V$ and $\frac{2.303 \ RT}{F} = 0.06 \ V$)

The $EMF$ of the cell $Cr|Cr^{3+}(0.1 \ M) \| Fe^{2+}(0.01 \ M)|Fe$ is: $(E^{\circ}_{Cr^{3+}|Cr} = -0.75 \ V, E^{\circ}_{Fe^{2+}|Fe} = -0.45 \ V)$ (in $V$)

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