The compressibility factor for a real gas at | vedclass

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(C) The van der Waals equation for a real gas is $(P + \frac{a}{V^2})(V - b) = RT$. At high pressure,the term $\frac{a}{V^2}$ is very small compared t

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$1+ \frac{Pb}{RT}$

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(C) The van der Waals equation for a real gas is $(P + \frac{a}{V^2})(V - b) = RT$. At high pressure,the term $\frac{a}{V^2}$ is very small compared to $P$ and can be neglected. Thus,the equation simplifies to $P(V - b) = RT$. Expanding this,we get $PV - Pb = RT$. Rearranging the terms,$PV = RT + Pb$. Dividing both sides by $RT$,we get $\frac{PV}{RT} = 1 + \frac{Pb}{RT}$. Since the compressibility factor $Z = \frac{PV}{RT}$,we have $Z = 1 + \frac{Pb}{RT}$. Therefore,at high pressure,$Z > 1$.

The compressibility factor for a real gas at high pressure is $:$

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