The compressibility factor $(Z)$ of a gas is greater than unity at $1 \, atm$ and $273 \, K$. Therefore:

  • A
    $V_m > 22.4 \, L$
  • B
    $V_m < 22.4 \, L$
  • C
    $V_m = 22.4 \, L$
  • D
    $V_m = 44.82 \, L$

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Difficult
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Consider the van der Waals constants,$a$ and $b$,for the following gases:
Gas $Ar$ $Ne$ $Kr$ $Xe$
$a / (atm \ dm^6 \ mol^{-2})$ $1.3$ $0.2$ $5.1$ $4.1$
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Which gas is expected to have the highest critical temperature?

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