The correct increasing order of trans-effect of the following species is:

  • A
    $NH_3 < CN^{-} < Br^{-} < C_6H_5^{-}$
  • B
    $NH_3 < Br^{-} < C_6H_5^{-} < CN^{-}$
  • C
    $Br^{-} < CN^{-} < NH_3 < C_6H_5^{-}$
  • D
    $CN^{-} < Br^{-} < C_6H_5^{-} < NH_3$

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Assertion : $[Al(H_2O)_6]^{3+}$ is a stronger acid than $[Mg(H_2O)_6]^{2+}$.
Reason : Size of $[Al(H_2O)_6]^{3+}$ is smaller than $[Mg(H_2O)_6]^{2+}$ and possesses more effective nuclear charge.

For the complex $ML_2$,the stepwise formation constants for the reactions:
$M + L \rightleftharpoons ML$
$ML + L \rightleftharpoons ML_2$
are $4$ and $3$ respectively. Hence,the overall stability constant for the reaction:
$M + 2L \rightleftharpoons ML_2$
is:

Arrange the following complexes in the correct increasing order of their electrical conductivity in aqueous solution:
$(I) [Pt(NH_3)_6]Cl_4$
$(II) [Cr(NH_3)_6]Cl_3$
$(III) [Co(NH_3)_4Cl_2]Cl$
$(IV) K_2[PtCl_6]$

Difficult
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The molar ionic conductance of the octahedral complexes:
$(i)$ $PtCl_4 \cdot 5 NH_3$ $(ii)$ $PtCl_4 \cdot 4 NH_3$ $(iii)$ $PtCl_4 \cdot 3 NH_3$ $(iv)$ $PtCl_4 \cdot 2 NH_3$
Follow the order:

Write the correct order of the spectrochemical series for the given ligands.

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