The correct order of the wavelength maxima of the absorption band in the ultraviolet-visible region for the given complexes is

  • A
    ${\left[ Co \left( NH _3\right)_5( Cl )\right]^{2+}<\left[ Co \left( NH _3\right)_5\left( H _2 O \right)\right]^{3+}<\left[ Co \left( NH _3\right)_6\right]^{3+}<\left[ Co ( CN )_6\right]^{3-}}$
  • B
    ${\left[ Co ( CN )_6\right]^{3-}<\left[ Co \left( NH _3\right)_6\right]^{3+}<\left[ Co \left( NH _3\right)_5\left( H _2 O \right)\right]^{3+}<\left[ Co \left( NH _3\right)_5( Cl )\right]^{2+}}$
  • C
    ${\left[ Co ( CN )_6\right]^{3-}<\left[ Co \left( NH _3\right)_5( Cl )\right]^{2+}<\left[ Co \left( NH _3\right)_5\left( H _2 O \right)\right]^{3+}<\left[ Co \left( NH _3\right)_6\right]^{3+}}$
  • D
    ${\left[ Co \left( NH _3\right)_6\right]^{3+}<\left[ Co ( CN )_6\right]^{3-}<\left[ Co \left( NH _3\right)_5( Cl )\right]^{2+}<\left[ Co \left( NH _3\right)_5\left( H _2 O \right)\right]^{3+}}$

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