The degree of dissociation $(\alpha)$ of a weak electrolyte,$A_xB_y$ is related to van't Hoff factor $(i)$ by the expression

Dimerisation of solute molecules in low dielectric constant solvent is due to

Solute $A$ associates in water. When $0.7 \ g$ of solute $A$ is dissolved in $42.0 \ g$ of water,it depresses the freezing point by $0.2^{\circ} C$. The percentage association of solute $A$ in water is $..... \ \%$.
[Given: Molar mass of $A = 93 \ g \ mol^{-1}$. Molal depression constant of water is $1.86 \ K \ kg \ mol^{-1}$]

The molecular weight of benzoic acid dissolved in benzene is found to be ............ $g/mol$.

$1.7920 \ g$ of $K_2SO_4$ is present in $1000 \ mL$ of solution. If such solution has an osmotic pressure of $0.680 \ bar$ at $26 \ ^\circ C$,then find out the van't Hoff factor value.

When $1.0 \ g$ of $KCl$ is dissolved in $200 \ g$ water,the decrease in freezing point of such solution is $0.24 \ K$,calculate Van't Hoff factor $(i)$ for such solution. $K_f$ of water $=$ $1.86 \ K \ kg \ mol^{-1}$.