The dissociation constants for acetic acid and $HCN$ at $25\,^{\circ}C$ are $1.5 \times 10^{-5}$ and $4.5 \times 10^{-10}$ respectively. The equilibrium constant for the equilibrium $CN^{-} + CH_3COOH \rightleftharpoons HCN + CH_3COO^{-}$ would be

  • A
    $3.0 \times 10^{-5}$
  • B
    $3.0 \times 10^{-4}$
  • C
    $3.0 \times 10^4$
  • D
    $3.0 \times 10^5$

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The ionization constant of $ClCH_{2}COOH$ is $1.35 \times 10^{-3}$. What will be the $pH$ of $0.1 \ M$ acid and its $0.1 \ M$ sodium salt solution?

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In which of the following mixed aqueous solutions, $pH = pK_{a}$ at equilibrium?
$(1)$ $100 \ mL$ of $0.1 \ M \ CH_{3}COOH + 100 \ mL$ of $0.1 \ M \ CH_{3}COONa$
$(2)$ $100 \ mL$ of $0.1 \ M \ CH_{3}COOH + 50 \ mL$ of $0.1 \ M \ NaOH$
$(3)$ $100 \ mL$ of $0.1 \ M \ CH_{3}COOH + 100 \ mL$ of $0.1 \ M \ NaOH$
$(4)$ $100 \ mL$ of $0.1 \ M \ CH_{3}COOH + 100 \ mL$ of $0.1 \ M \ NH_{3}$

On decreasing the $pH$ from $7$ to $2$,the solubility of a sparingly soluble salt $(MX)$ of a weak acid $(HX)$ increased from $10^{-4} \ mol \ L^{-1}$ to $10^{-3} \ mol \ L^{-1}$. The $pK_{a}$ of $HX$ is:

The decreasing order of electrical conductivity of the following aqueous solutions is:
$0.1 \ M$ Formic acid $(a)$
$0.1 \ M$ Acetic acid $(b)$
$0.1 \ M$ Benzoic acid $(c)$

If the equilibrium constant of $CH_3COOH + H_2O \rightleftharpoons CH_3COO^{-} + H_3O^{+}$ is $1.8 \times 10^{-5}$,what is the equilibrium constant for the reaction $CH_3COOH + OH^{-} \rightleftharpoons CH_3COO^{-} + H_2O$?

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