The entropy versus temperature plot for phases $\alpha$ and $\beta$ at $1 \ bar$ pressure is given. $S_T$ and $S_0$ are entropies of the phases at temperatures $T$ and $0 \ K$,respectively.
The transition temperature for $\alpha$ to $\beta$ phase change is $600 \ K$ and $C_{p, \beta} - C_{p, \alpha} = 1 \ J \ mol^{-1} \ K^{-1}$. Assume $(C_{p, \beta} - C_{p, \alpha})$ is independent of temperature in the range of $200$ to $700 \ K$. $C_{p, \alpha}$ and $C_{p, \beta}$ are heat capacities of $\alpha$ and $\beta$ phases,respectively.
$(1)$ The value of entropy change,$S_{\beta} - S_{\alpha}$ (in $J \ mol^{-1} \ K^{-1}$),at $300 \ K$ is. . . . . . .
$(2)$ The value of enthalpy change,$H_{\beta} - H_{\alpha}$ (in $J \ mol^{-1}$),at $300 \ K$ is.
[Use : $\ln 2 = 0.69$,Given : $S_{\beta} - S_{\alpha} = 0$ at $0 \ K$]

  • A
    $0.31, 300$
  • B
    $0.31, 400$
  • C
    $0.32, 500$
  • D
    $0.34, 600$

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Similar Questions

Match the List-$I$ with List-$II$
List-$I$ Thermodynamic Process List-$II$ Magnitude in $kJ$
$A$. Work done in reversible, isothermal expansion of $2 \ mol$ of ideal gas from $2 \ dm^3$ to $20 \ dm^3$ at $300 \ K$. $I$. $4$
$B$. Work done in irreversible isothermal expansion of $1 \ mol$ ideal gas from $1 \ m^3$ to $3 \ m^3$ at $300 \ K$ against a constant pressure of $3 \ kPa$. $II$. $11.5$
$C$. Change in internal energy for adiabatic expansion of a $1 \ mol$ ideal gas with change of temperature $= 320 \ K$ and $\overline{C}_V = \frac{3}{2} R$. $III$. $6$
$D$. Change in enthalpy at constant pressure of $1 \ mole$ ideal gas with change of temperature $= 337 \ K$ and $\overline{C}_P = \frac{5}{2} R$. $IV$. $7$

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For the following combustion reaction occurring in an automobile: $2C_{8}H_{18(g)} + 25O_{2(g)} \to 16CO_{2(g)} + 18H_{2}O_{(g)}$,what are the signs of $\Delta H$,$\Delta S$,and $\Delta G$?

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Calculate $\Delta H^{\circ}$ for the reaction, $Na_2O_{(s)} + SO_{3(g)} \longrightarrow Na_2SO_{4(s)}$, given the following reactions:
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