The equation that is incorrect is

  • A
    $(\Lambda_{m}^{0})_{NaBr} - (\Lambda_{m}^{0})_{NaI} = (\Lambda_{m}^{0})_{KBr} - (\Lambda_{m}^{0})_{NaBr}$
  • B
    $(\Lambda_{m}^{0})_{H_{2}O} = (\Lambda_{m}^{0})_{HCl} + (\Lambda_{m}^{0})_{NaOH} - (\Lambda_{m}^{0})_{NaCl}$
  • C
    $(\Lambda_{m}^{0})_{KCl} - (\Lambda_{m}^{0})_{NaCl} = (\Lambda_{m}^{0})_{KBr} - (\Lambda_{m}^{0})_{NaBr}$
  • D
    $(\Lambda_{m}^{0})_{NaBr} - (\Lambda_{m}^{0})_{NaCl} = (\Lambda_{m}^{0})_{KBr} - (\Lambda_{m}^{0})_{KCl}$

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Consider the cell reaction at $300 \ K$: $A_{(s)} + B^{2+}_{(aq)} \rightleftharpoons A^{2+}_{(aq)} + B_{(s)}$. Its $E^{\circ}$ is $1.0 \ V$. The $\Delta_{r}H^{\circ}$ of the reaction is $-163 \ kJ \ mol^{-1}$. What is $\Delta_{r}S^{\circ}$ (in $J \ K^{-1} \ mol^{-1}$) of the reaction? $(F = 96500 \ C \ mol^{-1})$

Based on the following information,arrange four metals $A, B, C$ and $D$ in order of decreasing ability to act as reducing agents:
$[I]$ Only $A, B$ and $C$ react with $1 \ M \ HCl$ to give $H_2 \ (g)$.
$[II]$ When $C$ is added to solutions of the other metal ions,metallic $B$ and $D$ are formed.
$[III]$ Metal $C$ does not reduce $A^{n+}$.

Using the standard electrode potentials,predict if the reaction between the following is feasible:
$(a) Fe_{(aq)}^{3+} \text{ and } I_{(aq)}^{-}$
$(b) Ag_{(aq)}^{+} \text{ and } Cu_{(s)}$
$(c) Fe_{(aq)}^{3+} \text{ and } Cu_{(s)}$
$(d) Ag_{(s)} \text{ and } Fe_{(aq)}^{3+}$
$(e) Br_{2(aq)} \text{ and } Fe_{(aq)}^{2+}$

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The molar conductivity of a solution of a weak acid $HX$ $(0.01 \ M)$ is $10$ times smaller than the molar conductivity of a solution of a weak acid $HY$ $(0.10 \ M)$. If $\lambda_{X^{-}}^0 \approx \lambda_{Y^{-}}^0$,the difference in their $pK_a$ values,$pK_a(HX) - pK_a(HY)$,is (consider degree of ionization of both acids to be $\ll 1$)

Match List-$I$ with List-$II$.
List-$I$ List-$II$
$A$. $Cd_{(s)} + 2 Ni(OH)_{3(s)} \rightarrow CdO_{(s)} + 2 Ni(OH)_{2(s)} + H_2O_{(l)}$ $I$. Primary battery
$B$. $Zn(Hg) + HgO_{(s)} \rightarrow ZnO_{(s)} + Hg_{(l)}$ $II$. Discharging of secondary battery
$C$. $2 PbSO_{4(s)} + 2 H_2O_{(l)} \rightarrow Pb_{(s)} + PbO_{2(s)} + 2 H_2SO_{4(aq)}$ $III$. Fuel cell
$D$. $2 H_{2(g)} + O_{2(g)} \rightarrow 2 H_2O_{(l)}$ $IV$. Charging of secondary battery

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