The experimental data for the reaction $2A + B_2 \longrightarrow 2AB$ is given below:
Exp. $[A] \ (mol \ L^{-1})$ $[B_2] \ (mol \ L^{-1})$ Rate $(mol \ L^{-1} \ S^{-1})$
$1$ $0.50$ $0.50$ $1.6 \times 10^{-4}$
$2$ $0.50$ $1.00$ $3.2 \times 10^{-4}$
$3$ $1.00$ $1.00$ $3.2 \times 10^{-4}$

Determine the rate law for the reaction.

  • A
    $r = K[A]^2[B_2]^2$
  • B
    $r = K[A]^2[B_2]$
  • C
    $r = K[B_2]$
  • D
    $r = K[B_2]^2$

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$[A]_0 / \text{mol } L^{-1}$ $t_{1/2} / \text{min}$
$0.100$ $200$
$0.025$ $100$

For a given reaction $R \rightarrow P$,$t_{1/2}$ is related to $[A]_0$ as given in the table:
Given: $\log 2 = 0.30$
Which of the following is true?
$A.$ The order of the reaction is $1/2$.
$B.$ If $[A]_0$ is $1 \text{ M}$,then $t_{1/2}$ is $200 \sqrt{10} \text{ min}$.
$C.$ The order of the reaction changes to $1$ if the concentration of reactant changes from $0.100 \text{ M}$ to $0.500 \text{ M}$.
$D.$ $t_{1/2}$ is $800 \text{ min}$ for $[A]_0 = 1.6 \text{ M}$.
Choose the correct answer from the options given below:

At what concentration of the reactant (in $M$) are the rate constants for first-order,second-order,and third-order reactions equal?

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