Which of the following is (are) an endothermic reaction?

  • A
    Conversion of graphite to diamond
  • B
    Decomposition of water
  • C
    Dehydrogenation of ethane to ethylene
  • D
    Both $(a), (b)$ and $(c)$

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For the complete combustion of ethanol,$C_2H_5OH_{(l)} + 3O_{2(g)} \rightarrow 2CO_{2(g)} + 3H_2O_{(l)}$,the amount of heat produced as measured in a bomb calorimeter is $1364.47 \ kJ \ mol^{-1}$ at $25 \ ^oC$. Assuming ideality,the enthalpy of combustion,$\Delta_cH$,for the reaction will be: $(R = 8.314 \ J \ K^{-1} \ mol^{-1})$ .....$kJ \ mol^{-1}$

When $1 \ g$ equivalent of a strong acid reacts with a strong base,the heat released is $13.5 \ kcal$. When $1 \ g$ equivalent of $H_2A$ is completely neutralized against a strong base,$13 \ kcal$ is released. When $1 \ g$ equivalent of $B(OH)_2$ is completely neutralized against a strong acid,$10 \ kcal$ of heat is released. Calculate the enthalpy change when $1 \ mole$ of $H_2A$ is completely neutralized by $B(OH)_2$ in $kcal$.

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Which of the following is/are true about the reversible isothermal expansion of an ideal gas?
$(a) \ \Delta U = 0$
$(b) \ q = 0$
$(c) \ \Delta T = 0$
$(d) \ q = 2.303 \ nRT \ \log_{10} \left( \frac{V_2}{V_1} \right)$

An ideal gas undergoes isothermal compression from $5\, m^3$ to $1\, m^3$ against a constant external pressure of $4\, Nm^{-2}$. Heat released in this process is used to increase the temperature of $1\, mole$ of $Al$. If molar heat capacity of $Al$ is $24\, J\, mol^{-1}\, K^{-1}$,the temperature of $Al$ increases by:

$6 \ g$ of graphite is burnt in a bomb calorimeter at $25^{\circ} C$ and $1 \ atm$ pressure. The temperature of water increased from $25^{\circ} C$ to $31^{\circ} C$. If $\Delta H$ of this reaction is $-248 \ kJ \ mol^{-1}$,find out $C_V$ (in $kJ \ K^{-1}$) of the bomb calorimeter.

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