The increasing order of reactivity among group-$1$ elements is $Li < Na < K < Rb < Cs$ whereas that among group-$17$ elements is $F > Cl > Br > I$. Explain.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(A) The elements of group-$1$ have only one electron in their outermost shells and therefore have a strong tendency to lose this electron. The tendency of these elements to lose the valence electron depends upon the ionization enthalpy. Since ionization enthalpy decreases down the group,the reactivity of group-$1$ elements increases in the order $Li < Na < K < Rb < Cs$.
On the other hand,the elements of group-$17$ have seven electrons in their respective valence shells and therefore have a strong tendency to accept one more electron. The tendency to accept additional electrons depends upon the electrode potentials of group-$17$ elements. The electrode potential of group-$17$ elements decreases from $F$ to $I$ $(F = +2.86 \ V, Cl = +1.36 \ V, Br = +1.08 \ V, I = +0.53 \ V)$ and therefore,their reactivities also decrease in the order $F > Cl > Br > I$.

Explore More

Similar Questions

In the reaction $2Br^- + X_2 \to Br_2 + 2X^-$,$X_2$ is .......

How does the metallic and non-metallic character vary on moving from left to right in a period?

In the reaction $2Br^- + X_2 \to Br_2 + 2X^-$,what is $X_2$?

The characteristics of elements $X$,$Y$ and $Z$ with atomic numbers,respectively,$33$,$53$ and $83$ are :

The correct order of acidic strength is:

Difficult
View Solution

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo