The isotherms of a gas are shown below:
Among the following:
$(i)$ At $T_1$,the gas cannot be liquefied.
$(ii)$ At point $B$,liquid starts to appear at $T_2$.
$(iii)$ $T_c$ is the highest temperature at which the gas can be liquefied.
$(iv)$ At point $A$,a small increase in pressure condenses the whole system to a liquid.
The correct statements are:

  • A
    only $(i)$ and $(ii)$
  • B
    only $(i), (iii)$ and $(iv)$
  • C
    only $(ii), (iii)$ and $(iv)$
  • D
    $(i), (ii), (iii)$ and $(iv)$

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For gases $W, X, Y$ and $Z$,the van der Waals constants are given below. Which gas has the highest critical temperature?
Gas$a$ (atm $L^2$ mol$^{-2}$)$b$ ($L$ mol$^{-1}$)
$W$$4.0$$0.027$
$X$$8.0$$0.030$
$Y$$6.0$$0.032$
$Z$$12.0$$0.027$

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