(B) In $CuSO_4 \cdot 5H_2O$,the structure consists of four water molecules coordinated directly to the $Cu^{2+}$ ion. The fifth water molecule is held

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(B) In $CuSO_4 \cdot 5H_2O$,the structure consists of four water molecules coordinated directly to the $Cu^{2+}$ ion. The fifth water molecule is held by hydrogen bonds between the $SO_4^{2-}$ ion and the coordinated water molecules. Therefore,only $1$ water molecule is involved in hydrogen bonding.