The observed osmotic pressure for a $0.10 \ M$ solution of $Fe(NH_4)_2(SO_4)_2$ at $25 \ ^oC$ is $10.8 \ atm$. The expected and experimental (observed) values of van't Hoff factor $(i)$ will be respectively: $(R = 0.082 \ L \ atm \ K^{-1} \ mol^{-1})$

$19.5 \text{ g}$ of fluoroacetic acid (molar mass = $78 \text{ g mol}^{-1}$) is dissolved in $500 \text{ g}$ of water at $298 \text{ K}$. The depression in the freezing point of water was $1^\circ\text{C}$. What is $K_a$ of fluoroacetic acid? (For water, $K_f = 1.86 \text{ K kg mol}^{-1}$). Assume molarity and molality to have same values.

In equimolar solutions of glucose,$NaCl$,and $BaCl_2$,the order of osmotic pressure is as follows:

The freezing point depression constant for water is $1.86 \, ^oC \, kg \, mol^{-1}.$ If $5.00 \, g$ of $Na_2SO_4$ is dissolved in $45.0 \, g$ of $H_2O,$ the freezing point is lowered by $3.82 \, ^oC.$ Calculate the van't Hoff factor for $Na_2SO_4.$

What is the percentage of dissociation of a $0.011 \ m$ aqueous solution of $K_3[Fe(CN)_6]$ having a freezing point of $-0.063 \ ^oC$? (Given: $K_f = 1.86 \ K \ kg \ mol^{-1}$ for water)

An aqueous solution is prepared by dissolving $0.1 \ mol$ of an ionic salt in $1.8 \ kg$ of water at $35^{\circ} C$. The salt remains $90 \%$ dissociated in the solution. The vapour pressure of the solution is $59.724 \ mm \ Hg$. Vapor pressure of water at $35^{\circ} C$ is $60.000 \ mm \ Hg$. The number of ions present per formula unit of the ionic salt is . . . . . .