The product of the following reaction is :

  • A
    Cyclohexanecarboxamide
  • B
    Cyclohexanecarbonitrile
  • C
    Isocyanocyclohexane
  • D
    $2-$Aminocyclohexanecarboxylic acid

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Arrange the following compounds in increasing order of their property as indicated:
$(i)$ Acetaldehyde,Acetone,Di-tert-butyl ketone,Methyl tert-butyl ketone (reactivity towards $HCN$)
$(ii)$ $CH_3CH_2CH(Br)COOH$,$CH_3CH(Br)CH_2COOH$,$(CH_3)_2CHCOOH$,$CH_3CH_2CH_2COOH$ (acid strength)
$(iii)$ Benzoic acid,$4$-Nitrobenzoic acid,$3,4$-Dinitrobenzoic acid,$4$-Methoxybenzoic acid (acid strength)

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What will be $X$ and $Y$ in the following reactions?

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Considering the reaction sequence given below,the correct statement$(s)$ is(are):
$A$. $P$ can be reduced to a primary alcohol using $NaBH_4$.
$B$. Treating $P$ with conc. $NH_4OH$ solution followed by acidification gives $Q$.
$C$. Treating $Q$ with a solution of $NaNO_2$ in aq. $HCl$ liberates $N_2$.
$D$. $P$ is more acidic than $CH_3CH_2COOH$.

Match the reactions given in Column-$I$ with their names in Column-$II$.
Column-$I$ (Reaction) Column-$II$ (Name)
$A$. $RCH_2COOH \rightarrow[H_2O]{X_2/P} RCH(X)COOH$ $i$. Decarboxylation
$B$. $RCOONa \rightarrow[NaOH, CaO, \Delta]{\text{soda lime}} RH$ $ii$. Grignard reaction
$C$. $RCOOH + R'OH \leftrightarrow{H^{+}} RCOOR' + H_2O$ $iii$. Hell-Volhard-Zelinsky reaction
$D$. $RMgX + R'CHO \rightarrow{H_3O^{+}} RCH(OH)R'$ $iv$. Esterification

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Match the reactions given in Column-$I$ with the appropriate reagents in Column-$II$.
| Column-$I$ (Reaction) | Column-$II$ (Reagent) |
| :--- | :--- |
| $(A)$ $2CH_3COOH \rightarrow (CH_3CO)_2O$ | $(i)$ $(I) NH_3, (II) \Delta, -H_2O$ |
| $(B)$ Phthalic acid $\rightarrow$ Phthalamide | $(ii)$ $(I) Br_2 / \text{red phosphorous}, (II) H_2O$ |
| $(C)$ $CH_3CH_2COOH \rightarrow CH_3CHBrCOOH$ | $(iii)$ $Br_2 / FeBr_3$ |
| $(D)$ Benzoic acid $\rightarrow$ $m$-Bromobenzoic acid | $(iv)$ $H^+, \Delta \text{ OR } P_2O_5, \Delta$ |

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