The reaction $A \xrightarrow{K} \text{Product}$ is zero order while the reaction $B \xrightarrow{K} \text{Product}$ is first order. For what initial concentration of $A$,the half-lives of the two reactions will be equal?

  • A
    $(\ln 4) \ M$
  • B
    $2 \ M$
  • C
    $2 \ \log 2 \ M$
  • D
    $\ln 2 \ M$

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Under the same reaction conditions, initial concentration of $1.386 \ mol \ dm^{-3}$ of a substance becomes half in $40 \ s$ and $20 \ s$ through first-order and zero-order kinetics respectively. Ratio $\left(\frac{k_{1}}{k_{0}}\right)$ of the rate constants for first-order $\left(k_{1}\right)$ and zero-order $\left(k_{0}\right)$ of the reactions is

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Match the rate expressions in List-$I$ for the decomposition of $X$ with the corresponding profiles provided in List-$II$. $X_s$ and $k$ are constants having appropriate units.

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