The reaction $2 NO_{2(g)} \rightleftharpoons N_2O_{4(g)}$ is at equilibrium in a closed $15 \ L$ vessel at $300 \ K$. The total weight of the mixture of $NO_2$ and $N_2O_4$ in the vessel is $64.4 \ g$. The equilibrium constant for the reaction is $K_p = 6.67$. Assuming ideal gas behavior,the total pressure in the vessel (in $atm$) is: [Given: Gas constant $R = 0.082 \ atm \ L \ K^{-1} \ mol^{-1}$]

$A$ $1 \, M$ solution of glucose reaches dissociation equilibrium according to the equation $C_6H_{12}O_6 \rightleftharpoons 6HCHO$. What is the concentration of $HCHO$ at equilibrium if the equilibrium constant $K_c$ for the formation of glucose from formaldehyde is $6 \times 10^{22}$?

At $473 \ K$, equilibrium constant $K_{c}$ for decomposition of phosphorus pentachloride, $PCl_{5}$, is $8.3 \times 10^{-3}$. If decomposition is depicted as,
$PCl_{5(g)} \rightleftharpoons PCl_{3(g)} + Cl_{2(g)}, \Delta_{r}H^{\Theta} = 124.0 \ kJ \ mol^{-1}$
$(a)$ Write an expression for $K_{c}$ for the reaction.
$(b)$ What is the value of $K_{c}$ for the reverse reaction at the same temperature?
$(c)$ What would be the effect on $K_{c}$ if $(i)$ more $PCl_{5}$ is added $(ii)$ pressure is increased $(iii)$ the temperature is increased?

Explain the relationship between the time taken to reach equilibrium and thermodynamics.

For a reaction; $A + B \rightleftharpoons C + D$,the initial concentrations of $A$ and $B$ are equal,but the equilibrium concentration of $C$ is twice that of the equilibrium concentration of $A$. The $K_c$ is:

An equilibrium shifts towards reactants at higher temperatures. Find the correct graph.