The standard electrode potential $({E^o})$ for $OCl^{-} / Cl^{-}$ and $Cl^{-} / \frac{1}{2}Cl_2$ respectively are $0.94 \ V$ and $-1.36 \ V$. The ${E^o}$ value for $OCl^{-} / \frac{1}{2}Cl_2$ will be ............... $V$.

  • A
    $-0.42$
  • B
    $-2.20$
  • C
    $0.52$
  • D
    $1.04$

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The standard electrode potential $(E^o)$ of $Cu^{2+}/Cu$ is $+0.34 \, V$,while that of $Zn^{2+}/Zn$ is $-0.76 \, V$. Explain the reason for this difference.

The standard electrode potentials are: $K^{+}/K = -2.93 \ V$,$Ag^{+}/Ag = 0.80 \ V$,$Hg^{2+}/Hg = 0.79 \ V$,$Mg^{2+}/Mg = -2.37 \ V$,$Cr^{3+}/Cr = -0.74 \ V$. Arrange these metals in the increasing order of their reducing power.

For the cell $Zn_{(s)} | Zn^{2+}_{(aq)} || M^{x+}_{(aq)} | M_{(s)}$,different half cells and their standard electrode potentials are given below:
$M^{x+}_{(aq)} / M_{(s)}$$Au^{3+}_{(aq)} / Au_{(s)}$$Ag^{+}_{(aq)} / Ag_{(s)}$$Fe^{3+}_{(aq)} / Fe^{2+}_{(aq)}$$Fe^{2+}_{(aq)} / Fe_{(s)}$
$E^o M^{x+} / M (V)$$1.40$$0.80$$0.77$$-0.44$

If $E^o Zn^{2+}/Zn = -0.76 \ V$,which cathode will give a maximum value of $E^o_{cell}$ per electron transferred?

The $E^o$ for the reduction of $NO_3^-$ ion in aqueous solution is $+0.96 \, V$. The $E^o$ values for several metal ions are given below:
$V^{2+}_{(aq)} + 2e^{-} \rightarrow V, \, E^o = -1.19 \, V;$
$Fe^{3+}_{(aq)} + 3e^{-} \rightarrow Fe, \, E^o = -0.04 \, V;$
$Au^{3+}_{(aq)} + 3e^{-} \rightarrow Au, \, E^o = +1.40 \, V;$
$Hg^{2+}_{(aq)} + 2e^{-} \rightarrow Hg, \, E^o = +0.86 \, V$
Which of the following pairs of metals is $NOT$ oxidized by $NO_3^-$ in aqueous solution?

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