The standard electrode potential of $Zn^{2+}/Zn$ is $-0.76\, V$ and that of $Cu^{2+}/Cu$ is $0.34\, V$. The emf $(V)$ and the free energy change $(kJ\, mol^{-1})$,respectively for a Daniell cell will be

Which of the following statements is correct regarding the cathode of an electrochemical cell?

In an electrochemical cell,

In the Daniell cell,$Zn|Zn^{2+} || Cu^{2+}|Cu$,when an external voltage is applied such that $E_{\text{external}} > E_{\text{cell}}$,current flows from.........

In a $Cu-Zn$ electrochemical cell:

Given below are two statements: one is labelled as Assertion $A$ and the other is labelled as Reason $R$.
Assertion $A$: In equation $\Delta_r G = -nFE_{\text{cell}}$,the value of $\Delta_r G$ depends on $n$.
Reason $R$: $E_{\text{cell}}$ is an intensive property and $\Delta_r G$ is an extensive property.
In the light of the above statements,choose the correct answer from the options given below: