The standard electrode potentials $E^o_{(I_2/I^{-})}$,$E^o_{(Br^{-}/Br_2)}$,and $E^o_{(Fe/Fe^{2+})}$ are respectively $+0.54 \ V$,$-1.09 \ V$,and $0.44 \ V$. On the basis of the above data,which of the following processes is non-spontaneous?

  • A
    $Br_2 + 2I^{-} \to 2Br^{-} + I_2$
  • B
    $Fe + Br_2 \to Fe^{2+} + 2Br^{-}$
  • C
    $Fe + I_2 \to Fe^{2+} + 2I^{-}$
  • D
    $I_2 + 2Br^{-} \to 2I^{-} + Br_2$

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Match the following:
List-$I$List-$II$
$(A)$ Potential of hydrogen electrode at $pH = 10$$(I)$ $0.76 \ V$
$(B)$ $Cu^{2+}|Cu$$(II)$ $0.059$
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$(a)$ $A-III, B-I, C-II, D-V$
$(b)$ $A-II, B-V, C-I, D-IV$
$(c)$ $A-III, B-IV, C-I, D-II$
$(d)$ $A-V, B-I, C-IV, D-II$

Choose the correct representation of conductometric titration of benzoic acid vs sodium hydroxide.

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Consider the change in oxidation state of Bromine corresponding to different $emf$ values as shown in the diagram below:
$BrO_4^{-}$ $\xrightarrow{1.82 \ V} BrO_3^{-}$ $\xrightarrow{1.5 \ V} HBrO$ $\xrightarrow{1.0652 \ V} Br_2$ $\xrightarrow{1.595 \ V} Br^{-}$
Then the species undergoing disproportionation is:

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