The vapour pressure of pure water is $92.5 \ mm$ at $300 \ K$. The vapour pressure of $1 \ molal$ solution of $X$ in water is :-

  • A
    $180$
  • B
    $90.86$
  • C
    $45.4$
  • D
    Unpredictable because molar mass is not given

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Assertion : If a liquid solute more volatile than the solvent is added to the solvent,the vapour pressure of the solution may increase i.e.,$p_s > p^o$.
Reason : In the presence of a more volatile liquid solute,only the solute will form the vapours and solvent will not.

Write the formula which expresses the relationship between the total pressure of a solution $(P_{total})$ and the mole fraction $(x_2)$ of the components,according to Raoult's law.

Two liquids $A$ and $B$ form a solution at $306 \ K$ that follows the equation $P \ (\text{in } atm) = 0.172X_A + 0.215$,where $P$ is the total vapor pressure of the solution and $X_A$ is the mole fraction of $A$. The vapor pressure of pure $B$ is ............ . (in $atm$)

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The vapour pressure of $30 \%$ $(w/v)$ aqueous solution of glucose is $...... \ mm \ Hg$ at $25^{\circ} \ C$. [Given : The density of $30 \%$ $(w/v)$ aqueous solution of glucose is $1.2 \ g \ cm^{-3}$ and vapour pressure of pure water is $24 \ mm \ Hg$.] (Molar mass of glucose is $180 \ g \ mol^{-1}$.)

At $50^{\circ} C$, the vapour pressure of pure benzene is $268 \ torr$. The number of moles of non-volatile solute per mole of benzene required to prepare a solution having a vapour pressure of $167 \ torr$ at the same temperature is (molar mass of benzene $= 78 \ g \ mol^{-1}$)

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