Toluene reacts with mixed acid at 25^{circ} C | vedclass

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Question

(C) The methyl group $(-CH_3)$ in toluene is an electron-donating group by inductive effect and hyperconjugation. It is an ortho- and para-directing g

Vedclass · Accepted Answer

Predominantly $o-$ nitrotoluene and $p-$ nitrotoluene

Vedclass · Answer

(C) The methyl group $(-CH_3)$ in toluene is an electron-donating group by inductive effect and hyperconjugation. It is an ortho- and para-directing group. Therefore, the nitration of toluene with a mixture of concentrated $HNO_3$ and $H_2SO_4$ at $25^{\circ} C$ yields a mixture of $o-$nitrotoluene and $p-$nitrotoluene as the major products, with a very small amount of $m-$nitrotoluene. Thus, the reaction produces predominantly $o-$nitrotoluene and $p-$nitrotoluene.

Toluene reacts with mixed acid at $25^{\circ} C$ to produce

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