What are $X$ and $Y$ respectively in the following reactions?

In the given reaction: $NH_2-CH_2-CH_2-NH_2 + C_2H_5OOC-COOC_2H_5 \xrightarrow{\text{Pyridine}} [X]$,$[X]$ will be:

Match Column-$I$ with Column-$II$ based on the $pK_a$ values of the given carboxylic acids:

Column-$I$	Column-$II$
$(A)$ $CF_3COOH$	$(i)$ $3.41$
$(B)$ Benzoic acid	$(ii)$ $4.76$
$(C)$ $CH_3COOH$	$(iii)$ $0.23$
$(D)$ $4$-nitrobenzoic acid	$(iv)$ $4.20$

Amongst the following, the total number of compounds soluble in aqueous $NaOH$ at room temperature is:
$(I)$ Benzaldehyde
$(II)$ $1$-Naphthol
$(III)$ $4$-(Dimethylamino)phenol
$(IV)$ $4$-Methylphenol
$(V)$ Benzoic acid
$(VI)$ $N,N$-Dimethylcyclohexanamine
$(VII)$ $1$-Naphthoic acid
$(VIII)$ $1,4$-Di-tert-butylbenzene
$(IX)$ $1$-Naphthylmethanol

Match the reactant in Column-$I$ with the reaction in Column-$II$:

Column-$I$	Column-$II$
$(i)$ Acetic acid	$(a)$ Stephen
$(ii)$ Sodium phenate	$(b)$ Friedel-Crafts
$(iii)$ Methyl cyanide	$(c)$ $HVZ$
$(iv)$ Toluene	$(d)$ Kolbe's

Ethanol on reaction with acetic anhydride gives