What do you mean by ortho and para directing groups? Explain the ortho and para directing effect by taking the example of any group.

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) Definition: In a monosubstituted benzene,if an incoming electrophile attacks the ortho and para positions with respect to the first substituent group $(Z)$,then the first group $(Z)$ is called an ortho and para directing group.
Examples: $-OH, -OCH_3, -NH_2, -CH_3, -C_2H_5, -NHCH_3, -NHR, -NHCOCH_3, -NHCOR$ etc.,are ortho and para directing groups.
$(b)$ Explanation of the directing properties of the $-OH$ group: The $-OH$ group (hydroxyl group) is ortho and para directing. This can be explained by the resonance structures of phenol,as shown below:
[Resonance structures of phenol showing increased electron density at ortho and para positions]
Due to the $+R$ effect of the $-OH$ group,the electron density increases at the ortho and para positions of the benzene ring. Consequently,an electrophile $(E^+)$ is more likely to attack these electron-rich positions,leading to ortho and para substitution products.

Explore More

Similar Questions

Benzene $ + (CH_3)_3C-CH_2Cl \xrightarrow{AlCl_3} \text{Major product}$

Difficult
View Solution

Which of the following hydrogens is most easily abstracted on reaction with bromine free radicals,$Br^{\cdot}$?

Benzene hexachloride is prepared from benzene and chlorine in the presence of sunlight by:

Identify compound $A$ in the following reaction:
$\text{Benzene} + \text{ozone (excess)}$ $\rightarrow \text{Benzenetrizonide}$ $\xrightarrow{A} \text{glyoxal}$

Explain the mechanism of the first and second steps of the general electrophilic substitution reaction for benzene.

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo