What is crystal field splitting energy? How does the magnitude of $\Delta_{o}$ decide the actual configuration of $d$-orbitals in a coordination entity?

Vedclass pdf generator app on play store
Vedclass iOS app on app store
(N/A) The degenerate $d$-orbitals (in a spherical field environment) split into two levels,i.e.,$e_{g}$ and $t_{2g}$,in the presence of ligands. The splitting of the degenerate levels due to the presence of ligands is called the crystal-field splitting,while the energy difference between the two levels ($e_{g}$ and $t_{2g}$) is called the crystal-field splitting energy. It is denoted by $\Delta_{o}$.
After the orbitals have split,the filling of the electrons takes place. After $1$ electron (each) has been filled in the three $t_{2g}$ orbitals,the filling of the fourth electron takes place in two ways. It can enter the $e_{g}$ orbital (giving rise to $t_{2g}^{3} e_{g}^{1}$ electronic configuration) or the pairing of the electrons can take place in the $t_{2g}$ orbitals (giving rise to $t_{2g}^{4} e_{g}^{0}$ electronic configuration). If the $\Delta_{o}$ value of a ligand is less than the pairing energy $(P)$,then the electrons enter the $e_{g}$ orbital. On the other hand,if the $\Delta_{o}$ value of a ligand is more than the pairing energy $(P)$,then the electrons enter the $t_{2g}$ orbital.

Explore More

Similar Questions

Zero value of $CFSE$ is observed in which of the following complexes?

The metal $d-$orbitals that directly face the ligands in $K_3[Co(CN)_6]$ are:

The order of energy absorbed,which is responsible for the color of the following complexes,is:

Identify the correct increasing order of field strength of ligands from the following.

Carbon donor ligands are strong ligands and usually form low spin complexes. Among the complexes given below,select the high spin complex.

Difficult
View Solution

Vedclass Products

For Students

Vedclass Test Series

Mock tests in real JEE/NEET style with performance analysis. 5-day free trial.

Start Free Trial
For Teachers

Exam Paper Generator

Generate Set A/B/C/D exam papers from 7.5L+ questions in 2 minutes. 3 chapters free.

Try Free
For Institutes

Online Exam Module

Live online exams with unlimited students, 360° analytics & white-label branding.

See Demo